"effex" Walnut Media is aggressive, especially when it's new and the granules are sharp. It works well when new on really dirty tarnished cases but will not produce a mirror shine finish. The more you use any media the longer it will take to achieve the initial new result so extend your times.
Corn Cob will produce a much better mirror finish to cases externally but it takes longer. New Corn Cob Media is already treated with a cleaner / polish.
In my opinion neither does a very good job at cleaning cases internally as once they fill with media it really doesn't move / tumble / vibrate much on the inside to remove spent / burnt powder residue.
There really is little reason to fully clean the inside of cartridge cases. The whole idea is nice looking cases but more important making them easier to inspect for faults, keeping reloading dies in good order and cleaner plus highly polished cases just look nice.
I have only used Walnut Media a couple of times for really old dirty cases so I have not ever cleaned it and not sure of what the results may be from washing but I have had the same Corn Cob Media for several years, it has cleaned many hundreds if not thousands of cases and the media has been washed several times in a stocking, in a bucket with detergent then spread on tray to dry. Once dry it goes back in the tumbler and I add some Lyman Brite, run the tumbler until it's all absorbed and there are no lumps what so ever. The Lyman Brite tends to give a high polish, mirror finish but also leaves a coating which I have found stops the cases from tarnishing in storage. I have some done a couple of years ago and they are as shiny as the day they were done.
Do not ever add any additive that is based on Ammonia which will attack the brass and make it brittle / crack. One such product is Brasso..
The older you Media gets, the longer it will take to clean your cases as the Media gets smoother and less agressive. After many years my norm is now to leave cases tumbling overnight, take them out in the morning and give them a wipe with a cotton cloth to remove any dust...they shine.
A much better and longer process is to Ultrasonic clean first, dry and put in the tumbler. Clean inside and mirror finish on the outside...non aggressive.
The US Cleaner and solution I use is the Clean And Shiny as depicted here....
http://www.accurateshooter.com/technica ... -cleaning/ Same US Unit, some tricks. Better results using clean water, not city water full of chemicals ie Tank water, distilled water etc.
I use 500ml Pyrex Beakers, no bigger and do not stack them full of cases nor too much solution. They sit in water in the US unit but remember this, the quantity of water in the US, the number of cases in the beaker and the amount of solution will need to be tested. Less is better. US works on exactly that, ultrasonic energy and the little tranducer can only produce so much energy to achieve the desired result. The liquids when you have it correct should look like they are boiling and the cases will vibrate around the beaker. That's when it's working best.
I give them several 480 second runs on the first solution, after one or two the solution should begin to look really dirty. I remove primers first but not in a normal sizing die. I also clean the primer pockets first.
I don't bother with Metho, just dry them on top of my wood heater, oven at 100c or in summer out in the sun on a black coloured steel tray.
One problem with cleaning too clean, it will increase the bullet neck tension since the carbon coating is gone so it's best to replace that lubricant and I dip a nylon case brush in a graphite bottle then run the brush down case necks for the next firing.
One warning.... washing cleaning media or playing with dirty US solutions, don't get it on your skin as the rubbish removed from cartridge cases contains some pretty nasty chemicals, one being arsnic. Keeps you hands away and /or wear protective gloves.