sneaker wrote:How old does it have to be for hardening to start?
That is very hard to say . There are many factors . Purity of brass , annealed or not after manufacture , storage time and conditions , exposure to chemicals that speed up the process , number of times fired , how much work hardening has been done by reloading die system , cleanliness of stored fired brass.
New annealed quality brass un loaded will start to harden somewhat at about 7 years in good storage conditions . However as the case neck is not under stress it may not develop full stress corrosion .
If loaded the stress of the seated bullet will change things and it has been know to start in reloads at about 7 to 10 years . There have been cases of it happening much quicker under certain poor circumstances . It is interesting to note the Military try to fire off their small arms ammo at about 7 years or less.
In stored reloads it can happen quicker but the condition is variable . Some case necks will shown shrinkage below the bullet base indicating increased neck tension and others might not . Some may split on firing and some may not . Some thin brass can be work hardened so much by expander ball dies that the next time they fire the necks split but it may note be full on stress corrosion at that point if the were left loaded for a long time then it takes over and they could split without even being fired .
Once the neck starts to shrink and apply excessive neck tension a condition called neck weld can happen where the bullet starts to bond with the case neck . Again this is very variable but it can happen to a few in the batch and chamber pressure can rise quite high to move the bullet on that shot . In some extreme cases the neck can tear off the case and go up the bore with the bullet .
I can show photos of some of these conditions on 10 year old reloads that I did a storage trial on . Moly coating a bullet does help to decrease the problem of excessive neck tension due to age hardening and in my trial no moly coated bullet developed any kind of neck weld either in 10 years .